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DiscussionStructure of Jatropha Oil http://www.ruralsementes.com.br/produtos/Valorisation%20of%20Jatropha%20curcas,%20Wageningen,%20March%2026-28,%2020.pdf
Jatropha Oil is a non-polar compound, as illustrated above. According to the general principal that "like dissolves like", non-polar solvents yield the best results when extracting non-polar oils like jatropha oil. Hexane is a non-polar compound and, aside from its low cost and abundance, is effective in returning the greatest percentage of oil following extraction, due to its polarity.
Hexane Ethyl Acetate ![]() ![]() Hexane:
http://www.hull.ac.uk/chemistry/masspec3/unknown4answermol.html Ethyl
acetate: http://commons.wikimedia.org/wiki/File:Ethyl_acetate2.png Ethanol Ethanol:
http://commons.wikimedia.org/wiki/File:Ethanol-structure.png Ethanol, however, is not acceptable as an alternative to hexane, as it was very difficult to remove from the oil once the extraction experiment was complete. Ethanol has a polar (right side of the above diagram) and non-polar end (left side). The non-polar end extracts jatropha oil, but the polar end enables it to extract other organic compounds, resulting in highly impure oil and making filtration very difficult. The final amount of oil after evaporation of the solvent, and possibly some oil that was still dissolved within, was 0.5 g per 10 mL sample. Jatropha ethanol had a tendency to foam during pipetting, indicating dissolved impurities, and results from the OD test of Jatropha ethanol also show many impurities in the oil, as the OD number is 0.693 at 600nm, twice that of either Jatropha ethyl acetate or Jatropha hexane.
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