PVC Bioplasticizers by Robyn Thom and Thomas Sun

 

 

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  Statistical Analysis
 

1. T-Test

               A T-test was performed to determine whether the difference in deflection between PVCs with safflower oil and DEHP at 10% and 40% concentrations were significantly different. 

A. At 10% Concentration

Deflection of Safflower Oil 10%

X

X - μ

(X – μ)^2

2

-.1

.01

2.3

.2

.04

2

-.1

.01

Total = 0.06

 

= (0.06/2)^1/2 = 0.173

From table, t  = 2.920

Error = ts          = 2.920 (0.173)           = 0.168
           n                       3

So, the error is 0.06 + 0.168 and the range is -0.108 – 0.228

Deflection of DEHP 10%

X

X - μ

(X – μ)^2

2

0.33

.1089

1.8

-0.17

.0289

2.1

0.13

.0169

Total = 0.1547

 

= (0.1547/2)^1/2 = 0.278

From table, t  = 2.920

Error = ts          = 2.920 (0.278)           = 0.271
           n                       3

So, the error is 0.1547 + 0.271 and the range is -0.1163  – 0.4257

The ranges -0.108 – 0.228 and -0.1163  – 0.4257 overlap, so the results are not significantly different.  From this, we can conclude that at the 10% plasticizer concentration, the effect of safflower oil on deflection is not significantly different from DEHP, and thus, can be seen as a viable alternative.

 

B. At 40% Concentration 

Deflection of Safflower Oil 40%

X

X - μ

(X – μ)^2

9.8

.1

.01

10.0

.1

.01

9.9

0

0

Total = 0.02

 

= (0.02/2)^1/2 = 0.1

From table, t  = 2.920

Error = ts          = 2.920 (0.1)           = 0.0973
           n                     3

So, the error is 0.02 + 0.0973 and the range is -0.0773 – 0.1173

Deflection of DEHP 40%

X

X - μ

(X – μ)^2

14

0.2

.04

13.8

0

0

13.6

-0.2

.04

Total = 0.08

= (0.08/2)^1/2 = 0.200

From table, t  = 2.920

Error = ts          = 2.920 (0.200)           = 0.195
           n                      3

So, the error is 0.08 + 0.195 and the range is -0.115  – 0.275 

The ranges -0.0773 – 0.1173 and -0.115  – 0.275 overlap, so the results are not significantly different.  From this, we can conclude that at the 40% plasticizer concentration, the effect of safflower oil on deflection is not significantly different from DEHP, and thus, can be seen as a viable alternative. 

After performing the T-test at both 10% and 40% concentrations for safflower oil and DEHP, it was found that the results from the deflection test were not significantly different.  Thus, safflower oil can be seen as a viable alternative for DEHP in enhancing flexibility.

2. Spearman’s Rank Correlating Elastic Modulus and Deflection

Hypothesis: From the above scatter plot, there seems to be a fairly strong negative correlation between elastic modulus and deflection.

Independent Variable

Rank**

Dependent Variable

Rank

d

d^2

1.1

14

2774.7

6

8

64

2.1

9

1876.55

9

0

0

8.2

4

696.95

18

-14

196

6.3

6

964.83

15

-9

81

9.9

2

420.52

20

-18

324

0.53

17

1964.51

7

10

100

1.9

11

1675.91

10

1

1

3.07

8

1547.23

14

-6

36

5.93

7

960.52

16

-9

81

1.03

15

1964.51

7

8

64

1.9

11

1587.48

13

-2

4

0.63

16

3561.25

4

12

144

0.3

19

3785.82

2

17

289

1.4

13

1647.95

10.5

2.5

6.25

0.4

18

3302.39

5

13

169

0.23

20

3730.45

3

17

289

0.1

21

3860.48

1

20

400

1.97

10

1647.95

10.5

-0.5

0.25

6.77

5

865.72

17

-12

144

9.17

3

621.45

19

-16

256

13.8

1

317.29

21

-20

400

 Rs = -0.72134

Test of Significance: When the Rs value is plotted on the significance graph, it appears within the acceptance level with a less than 0.1% correlation by chance.

From this statistical test, we found that the higher the deflection value, the lower the Elastic Modulus value. Thus, the more flexible a PVC film is, the more elastic it is. 

 

  Robyn Thom
  Thomas Sun
  Sir Winston Churchill Secondary School

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